In this project, we will focus on the physico-chemical processes of crystalline catalytic solids, like Metal-organic Frameworks and zeolites. Using advanced in-situ Scanning Probe Microscopy techniques, like liquid-phase Atomic Force Microscopy, Kelvin Probe Force Microscopy and Nano-IR Spectroscopy, the nucleation and growth, stability and catalytic activity are studied. These techniques, complemented by UV-Vis and IR spectroscopy, yield a better understanding of the properties of such solid thin films or single crystals.
Publications
Mandemaker, L D B; Rivera-Torrente, M; Geitner, R; Vis, C M; Weckhuysen, B M
In Situ Spectroscopy of Calcium Fluoride Anchored Metal–Organic Framework Thin Films during Gas Sorption Journal Article
In: Angewandte Chemie - International Edition, 59 (44), pp. 19545-19552, 2020.
@article{Mandemaker202019545,
title = {In Situ Spectroscopy of Calcium Fluoride Anchored Metal–Organic Framework Thin Films during Gas Sorption},
author = {L D B Mandemaker and M Rivera-Torrente and R Geitner and C M Vis and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85087888883&doi=10.1002%2fanie.202006347&partnerID=40&md5=e59c4e69a15be6be02bdc786e77822d5},
year = {2020},
date = {2020-01-01},
journal = {Angewandte Chemie - International Edition},
volume = {59},
number = {44},
pages = {19545-19552},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Rivera-Torrente, M; Mandemaker, L D B; Filez, M; Delen, G; Seoane, B; Meirer, F; Weckhuysen, B M
Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: Formation, metal sites in catalysis and thin films Journal Article
In: Chemical Society Reviews, 49 (18), pp. 6694-6732, 2020.
@article{Rivera-Torrente20206694,
title = {Spectroscopy, microscopy, diffraction and scattering of archetypal MOFs: Formation, metal sites in catalysis and thin films},
author = {M Rivera-Torrente and L D B Mandemaker and M Filez and G Delen and B Seoane and F Meirer and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85091469630&doi=10.1039%2fd0cs00635a&partnerID=40&md5=c559c50e306f60dd0bf8554933b84507},
year = {2020},
date = {2020-01-01},
journal = {Chemical Society Reviews},
volume = {49},
number = {18},
pages = {6694-6732},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Wijten, J H J; Mandemaker, L D B; van Eeden, T C; Dubbeld, J E; Weckhuysen, B M
In Situ Study on Ni–Mo Stability in a Water-Splitting Device: Effect of Catalyst Substrate and Electric Potential Journal Article
In: ChemSusChem, 13 (12), pp. 3172-3179, 2020.
@article{Wijten20203172,
title = {In Situ Study on Ni–Mo Stability in a Water-Splitting Device: Effect of Catalyst Substrate and Electric Potential},
author = {J H J Wijten and L D B Mandemaker and T C van Eeden and J E Dubbeld and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85084472977&doi=10.1002%2fcssc.202000678&partnerID=40&md5=948828e290265984356591a4a31d30cc},
year = {2020},
date = {2020-01-01},
journal = {ChemSusChem},
volume = {13},
number = {12},
pages = {3172-3179},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Mandemaker, L D B; Rivera-Torrente, M; Delen, G; Hofmann, J P; Lorenz, M; Belianinov, A; Weckhuysen, B M
Nanoweb Surface-Mounted Metal–Organic Framework Films with Tunable Amounts of Acid Sites as Tailored Catalysts Journal Article
In: Chemistry - A European Journal, 26 (3), pp. 691-698, 2020.
@article{Mandemaker2020691,
title = {Nanoweb Surface-Mounted Metal–Organic Framework Films with Tunable Amounts of Acid Sites as Tailored Catalysts},
author = {L D B Mandemaker and M Rivera-Torrente and G Delen and J P Hofmann and M Lorenz and A Belianinov and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85076377521&doi=10.1002%2fchem.201903761&partnerID=40&md5=e0262990da8bd937363ff7b496923f58},
year = {2020},
date = {2020-01-01},
journal = {Chemistry - A European Journal},
volume = {26},
number = {3},
pages = {691-698},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Amirilargani, M; Yokota, G N; Vermeij, G H; Merlet, R B; Delen, G; Mandemaker, L D B; Weckhuysen, B M; Winnubst, L; Nijmeijer, A; de Smet, L C P M; Sudhölter, E J R
Melamine-Based Microporous Organic Framework Thin Films on an Alumina Membrane for High-Flux Organic Solvent Nanofiltration Journal Article
In: ChemSusChem, 13 (1), pp. 136-140, 2020.
@article{Amirilargani2020136,
title = {Melamine-Based Microporous Organic Framework Thin Films on an Alumina Membrane for High-Flux Organic Solvent Nanofiltration},
author = {M Amirilargani and G N Yokota and G H Vermeij and R B Merlet and G Delen and L D B Mandemaker and B M Weckhuysen and L Winnubst and A Nijmeijer and L C P M de Smet and E J R Sudhölter},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85074068919&doi=10.1002%2fcssc.201902341&partnerID=40&md5=93bdea2a3bb010d0e6ff73bc9ed6e420},
year = {2020},
date = {2020-01-01},
journal = {ChemSusChem},
volume = {13},
number = {1},
pages = {136-140},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Wijten, J H J; Riemersma, R L; Gauthier, J; Mandemaker, L D B; Verhoeven, M W G M T; Hofmann, J P; Chan, K; Weckhuysen, B M
Electrolyte Effects on the Stability of Ni−Mo Cathodes for the Hydrogen Evolution Reaction Journal Article
In: ChemSusChem, 12 (15), pp. 3491-3500, 2019.
@article{Wijten20193491,
title = {Electrolyte Effects on the Stability of Ni−Mo Cathodes for the Hydrogen Evolution Reaction},
author = {J H J Wijten and R L Riemersma and J Gauthier and L D B Mandemaker and M W G M T Verhoeven and J P Hofmann and K Chan and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85068214527&doi=10.1002%2fcssc.201900617&partnerID=40&md5=43079341bf6a2860614a9d9e5e04ddb5},
year = {2019},
date = {2019-01-01},
journal = {ChemSusChem},
volume = {12},
number = {15},
pages = {3491-3500},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Brand, R P; Mandemaker, L D B; Delen, G; Rijnveld, N; Weckhuysen, B M
Behavior of a Metal Organic Framework Thin-Film at Elevated Temperature and Pressure as Studied with an Autoclave-Inserted Atomic Force Microscope Journal Article
In: ChemPhysChem, 19 (18), pp. 2397-2404, 2018.
@article{Brand20182397,
title = {Behavior of a Metal Organic Framework Thin-Film at Elevated Temperature and Pressure as Studied with an Autoclave-Inserted Atomic Force Microscope},
author = {R P Brand and L D B Mandemaker and G Delen and N Rijnveld and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85053197104&doi=10.1002%2fcphc.201800284&partnerID=40&md5=9a0a35ee4a02b27a0534c496df8620fa},
year = {2018},
date = {2018-01-01},
journal = {ChemPhysChem},
volume = {19},
number = {18},
pages = {2397-2404},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Fu, D; Schmidt, J E; Pletcher, P; Karakiliç, P; Ye, X; Vis, C M; Bruijnincx, P C A; Filez, M; Mandemaker, L D B; Winnubst, L; Weckhuysen, B M
Uniformly Oriented Zeolite ZSM-5 Membranes with Tunable Wettability on a Porous Ceramic Journal Article
In: Angewandte Chemie - International Edition, 57 (38), pp. 12458-12462, 2018.
@article{Fu201812458,
title = {Uniformly Oriented Zeolite ZSM-5 Membranes with Tunable Wettability on a Porous Ceramic},
author = {D Fu and J E Schmidt and P Pletcher and P Karakiliç and X Ye and C M Vis and P C A Bruijnincx and M Filez and L D B Mandemaker and L Winnubst and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85052433247&doi=10.1002%2fanie.201806361&partnerID=40&md5=51944d7762f58717cd15d3b717a28244},
year = {2018},
date = {2018-01-01},
journal = {Angewandte Chemie - International Edition},
volume = {57},
number = {38},
pages = {12458-12462},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Mandemaker, L D B; Filez, M; Delen, G; Tan, H; Zhang, X; Lohse, D; Weckhuysen, B M
Time-Resolved in Situ Liquid-Phase Atomic Force Microscopy and Infrared Nanospectroscopy during the Formation of Metal-Organic Framework Thin Films Journal Article
In: Journal of Physical Chemistry Letters, 9 (8), pp. 1838-1844, 2018.
@article{Mandemaker20181838,
title = {Time-Resolved in Situ Liquid-Phase Atomic Force Microscopy and Infrared Nanospectroscopy during the Formation of Metal-Organic Framework Thin Films},
author = {L D B Mandemaker and M Filez and G Delen and H Tan and X Zhang and D Lohse and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85045749439&doi=10.1021%2facs.jpclett.8b00203&partnerID=40&md5=e80c1642cec186be81334f5aff8d67c9},
year = {2018},
date = {2018-01-01},
journal = {Journal of Physical Chemistry Letters},
volume = {9},
number = {8},
pages = {1838-1844},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Delen, G; Ristanović, Z; Mandemaker, L D B; Weckhuysen, B M
Mechanistic Insights into Growth of Surface-Mounted Metal-Organic Framework Films Resolved by Infrared (Nano-) Spectroscopy Journal Article
In: Chemistry - A European Journal, 24 (1), pp. 187-195, 2018.
@article{Delen2018187,
title = {Mechanistic Insights into Growth of Surface-Mounted Metal-Organic Framework Films Resolved by Infrared (Nano-) Spectroscopy},
author = {G Delen and Z Ristanović and L D B Mandemaker and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85034766906&doi=10.1002%2fchem.201704190&partnerID=40&md5=43b09ede00c00897a6e2eed3f87ab6cc},
year = {2018},
date = {2018-01-01},
journal = {Chemistry - A European Journal},
volume = {24},
number = {1},
pages = {187-195},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
