Study Co-based Fischer-Tropsch Synthesis (FTS) catalysts by synchrotron-based microscopy and spectroscopy techniques to unravel the activation and deactivation mechanisms. In situ/operando Scanning Transmission X-ray Microscopy (STXM) is used for the elemental mapping of the Co, O, Ti and C on single catalyst particles. Operando hard X-ray Absorption Spectroscopy (XAS) is used to follow long-term activation and deactivation mechanisms of the Co particles via the X-ray Absorption Fine Structure (XAFS).
Publications
Ye, X; Schmidt, J E; Wang, R -P; van Ravenhorst, I K; Oord, R; Chen, T; de Groot, F; Meirer, F; Weckhuysen, B M
Deactivation of Cu-Exchanged Automotive-Emission NH3-SCR Catalysts Elucidated with Nanoscale Resolution Using Scanning Transmission X-ray Microscopy Journal Article
In: Angewandte Chemie - International Edition, vol. 59, no. 36, pp. 15610-15617, 2020.
@article{Ye202015610,
title = {Deactivation of Cu-Exchanged Automotive-Emission NH3-SCR Catalysts Elucidated with Nanoscale Resolution Using Scanning Transmission X-ray Microscopy},
author = {X Ye and J E Schmidt and R -P Wang and I K van Ravenhorst and R Oord and T Chen and F de Groot and F Meirer and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85080108194&doi=10.1002%2fanie.201916554&partnerID=40&md5=50cf61c5fe93eb92da42983b691c89f9},
year = {2020},
date = {2020-01-01},
journal = {Angewandte Chemie - International Edition},
volume = {59},
number = {36},
pages = {15610-15617},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
van Ravenhorst, I K; Geitenbeek, R G; van der Eerden, M J; van Omme, J Tijn; Garza, H H Peréz; Meirer, F; Meijerink, A; Weckhuysen, B M
In Situ Local Temperature Mapping in Microscopy Nano-Reactors with Luminescence Thermometry Journal Article
In: ChemCatChem, vol. 11, no. 22, pp. 5505-5512, 2019.
@article{vanRavenhorst20195505,
title = {In Situ Local Temperature Mapping in Microscopy Nano-Reactors with Luminescence Thermometry},
author = {I K van Ravenhorst and R G Geitenbeek and M J van der Eerden and J Tijn van Omme and H H Peréz Garza and F Meirer and A Meijerink and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85074096418&doi=10.1002%2fcctc.201900985&partnerID=40&md5=db4420627600735fa97c01d1113fe810},
year = {2019},
date = {2019-01-01},
journal = {ChemCatChem},
volume = {11},
number = {22},
pages = {5505-5512},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Schmidt, J E; Ye, X; van Ravenhorst, I K; Oord, R; Shapiro, D A; Yu, Y -S; Bare, S R; Meirer, F; Poplawsky, J D; Weckhuysen, B M
Probing the Location and Speciation of Elements in Zeolites with Correlated Atom Probe Tomography and Scanning Transmission X-Ray Microscopy Journal Article
In: ChemCatChem, vol. 11, no. 1, pp. 488-494, 2019.
@article{Schmidt2019488,
title = {Probing the Location and Speciation of Elements in Zeolites with Correlated Atom Probe Tomography and Scanning Transmission X-Ray Microscopy},
author = {J E Schmidt and X Ye and I K van Ravenhorst and R Oord and D A Shapiro and Y -S Yu and S R Bare and F Meirer and J D Poplawsky and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85055744140&doi=10.1002%2fcctc.201801378&partnerID=40&md5=f9b325e555cd15353736b0bd7f076cc7},
year = {2019},
date = {2019-01-01},
journal = {ChemCatChem},
volume = {11},
number = {1},
pages = {488-494},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
van Ravenhorst, I K; Vogt, C; Oosterbeek, H; Bossers, K W; Moya-Cancino, J G; van Bavel, A P; van der Eerden, A M J; Vine, D; de Groot, F M F; Meirer, F; Weckhuysen, B M
Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy Journal Article
In: Angewandte Chemie - International Edition, vol. 57, no. 37, pp. 11957-11962, 2018.
@article{vanRavenhorst201811957,
title = {Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy},
author = {I K van Ravenhorst and C Vogt and H Oosterbeek and K W Bossers and J G Moya-Cancino and A P van Bavel and A M J van der Eerden and D Vine and F M F de Groot and F Meirer and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-85052744175&doi=10.1002%2fanie.201806354&partnerID=40&md5=c693bdb1d1d0168b37feb70f919f5a65},
year = {2018},
date = {2018-01-01},
journal = {Angewandte Chemie - International Edition},
volume = {57},
number = {37},
pages = {11957-11962},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Cicmil, D; Ravenhorst, I K Van; Meeuwissen, J; Vantomme, A; Weckhuysen, B M
Structure-performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: Tuning the selectivity towards 1-hexene Journal Article
In: Catalysis Science and Technology, vol. 6, no. 3, pp. 731-743, 2016.
@article{Cicmil2016731,
title = {Structure-performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: Tuning the selectivity towards 1-hexene},
author = {D Cicmil and I K Van Ravenhorst and J Meeuwissen and A Vantomme and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84957601324&doi=10.1039%2fc5cy01512j&partnerID=40&md5=58a9778cda9f435f2b81d60fb1d6bbeb},
doi = {10.1039/c5cy01512j},
year = {2016},
date = {2016-01-01},
journal = {Catalysis Science and Technology},
volume = {6},
number = {3},
pages = {731-743},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
Cicmil, D; Meeuwissen, J; Vantomme, A; Wang, J; Ravenhorst, I K Van; Bij, H E Van Der; Muñoz-Murillo, A; Weckhuysen, B M
Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding Journal Article
In: Angewandte Chemie - International Edition, vol. 54, no. 44, pp. 13073-13079, 2015.
@article{Cicmil201513073,
title = {Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding},
author = {D Cicmil and J Meeuwissen and A Vantomme and J Wang and I K Van Ravenhorst and H E Van Der Bij and A Muñoz-Murillo and B M Weckhuysen},
url = {https://www.scopus.com/inward/record.uri?eid=2-s2.0-84945488141&doi=10.1002%2fanie.201506718&partnerID=40&md5=592f5e86f30fa73ee53734484a2c8594},
doi = {10.1002/anie.201506718},
year = {2015},
date = {2015-01-01},
journal = {Angewandte Chemie - International Edition},
volume = {54},
number = {44},
pages = {13073-13079},
keywords = {},
pubstate = {published},
tppubtype = {article}
}
