Study Co-based Fischer-Tropsch Synthesis (FTS) catalysts by synchrotron-based microscopy and spectroscopy techniques to unravel the activation and deactivation mechanisms. In situ/operando Scanning Transmission X-ray Microscopy (STXM) is used for the elemental mapping of the Co, O, Ti and C on single catalyst particles. Operando hard X-ray Absorption Spectroscopy (XAS) is used to follow long-term activation and deactivation mechanisms of the Co particles via the X-ray Absorption Fine Structure (XAFS).
On the Cobalt Carbide Formation in a Co/TiO2Fischer-Tropsch Synthesis Catalyst as Studied by High-Pressure, Long-Term Operando X-ray Absorption and Diffraction Journal Article
ACS Catalysis, pp. 2956-2967, 2021.
Deactivation of Cu-Exchanged Automotive-Emission NH3-SCR Catalysts Elucidated with Nanoscale Resolution Using Scanning Transmission X-ray Microscopy Journal Article
Angewandte Chemie - International Edition, 59 (36), pp. 15610-15617, 2020.
In Situ Local Temperature Mapping in Microscopy Nano-Reactors with Luminescence Thermometry Journal Article
ChemCatChem, 11 (22), pp. 5505-5512, 2019.
Probing the Location and Speciation of Elements in Zeolites with Correlated Atom Probe Tomography and Scanning Transmission X-Ray Microscopy Journal Article
ChemCatChem, 11 (1), pp. 488-494, 2019.
Capturing the Genesis of an Active Fischer–Tropsch Synthesis Catalyst with Operando X-ray Nanospectroscopy Journal Article
Angewandte Chemie - International Edition, 57 (37), pp. 11957-11962, 2018.
Structure-performance relationships of Cr/Ti/SiO2 catalysts modified with TEAl for oligomerisation of ethylene: Tuning the selectivity towards 1-hexene Journal Article
Catalysis Science and Technology, 6 (3), pp. 731-743, 2016.
Polyethylene with Reverse Co-monomer Incorporation: From an Industrial Serendipitous Discovery to Fundamental Understanding Journal Article
Angewandte Chemie - International Edition, 54 (44), pp. 13073-13079, 2015.