dr. Mario De bruyn

dr. Mario De bruyn
+16084214753
debruyn@wisc.edu

The project is a collaboration between the University of Wisconsin at Madison (USA) and the Inorganic Chemistry and Catalysis group at Utrecht University (the Netherlands). The first two years of the project will be conducted at the University of Wisconsin in the group of Prof. James Dumesic, and will concern the making of heterogeneous catalysts using atomic layer deposition (ALD).
In the third year, Dr. De bruyn will move to the group of Prof. Bert Weckhuysen. Then the prime focus of the project will shift towards the characterization of the developed ALD catalysts using advanced Raman/IR spectroscopy. Additionally, an overarching goal of this project is to use the ALD catalysts in hydrodeoxygenation and hydrogenation reactions and more specifically of levoglucosenone, a rising specialty chemical directly obtainable from cellulose

Publications

Kim, S; Bruyn, De M; Louvain, N; Alauzun, J G; Brun, N; Macquarrie, D J; Boury, B; Stievano, L; Mutin, P H; Monconduit, L

Green electrode processing using a seaweed-derived mesoporous carbon additive and binder for LiMn 2 O 4 and LiNi 1/3 Mn 1/3 Co 1/3 O 2 lithium ion battery electrodes Journal Article

Sustainable Energy and Fuels, 3 (2), pp. 450-456, 2019.

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Bruyn, De M; Budarin, V L; Misefari, A; Shimizu, S; Fish, H; Cockett, M; Hunt, A J; Hofstetter, H; Weckhuysen, B M; Clark, J H; Macquarrie, D J

Geminal Diol of Dihydrolevoglucosenone as a Switchable Hydrotrope: A Continuum of Green Nanostructured Solvents Journal Article

ACS Sustainable Chemistry and Engineering, 7 (8), pp. 7878-7883, 2019.

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Krishna, S H; Huang, K; Barnett, K J; He, J; Maravelias, C T; Dumesic, J A; Huber, G W; bruyn, De M; Weckhuysen, B M

Oxygenated commodity chemicals from chemo-catalytic conversion of biomass derived heterocycles Journal Article

AIChE Journal, 64 (6), pp. 1910-1922, 2018.

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Krishna, S H; Bruyn, De M; Schmidt, Z R; Weckhuysen, B M; Dumesic, J A; Huber, G W

Catalytic production of hexane-1,2,5,6-tetrol from bio-renewable levoglucosanol in water: Effect of metal and acid sites on (stereo)-selectivity Journal Article

Green Chemistry, 20 (19), pp. 4557-4565, 2018.

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Kim, S; bruyn, De M; Alauzun, J G; Louvain, N; Brun, N; Macquarrie, D J; Stievano, L; Boury, B; Mutin, P H; Monconduit, L

Alginic acid-derived mesoporous carbonaceous materials (Starbon ® ) as negative electrodes for lithium ion batteries: Importance of porosity and electronic conductivity Journal Article

Journal of Power Sources, 406 , pp. 18-25, 2018.

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Kim, S; Bruyn, De M; Alauzun, J G; Louvain, N; Brun, N; Macquarrie, D J; Stievano, L; Boury, B; Monconduit, L; Mutin, P H

Alginic acid-derived mesoporous carbon (Starbon®) as template and reducing agent for the hydrothermal synthesis of mesoporous LiMn2O4 grafted with carbonaceous species Journal Article

Journal of Materials Chemistry A, 6 (29), pp. 14392-14399, 2018.

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García, A M; Budarin, V L; Zhou, Y; Bruyn, De M; Hunt, A J; Lari, L; Lazarov, V K; Salavagione, H J; Morales, E; Ellis, G J; Clark, J H; Shuttleworth, P S

Monolithic mesoporous graphitic composites as super capacitors: From Starbons to Starenes® Journal Article

Journal of Materials Chemistry A, 6 (3), pp. 1119-1127, 2018.

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Bruyn, De M; Budarin, V L; Sturm, G S J; Stefanidis, G D; Radoiu, M; Stankiewicz, A; Macquarrie, D J

Subtle Microwave-Induced Overheating Effects in an Industrial Demethylation Reaction and Their Direct Use in the Development of an Innovative Microwave Reactor Journal Article

Journal of the American Chemical Society, 139 (15), pp. 5431-5436, 2017.

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Salavagione, H J; Sherwood, J; Bruyn, De M; Budarin, V L; Ellis, G J; Clark, J H; Shuttleworth, P S

Identification of high performance solvents for the sustainable processing of graphene Journal Article

Green Chemistry, 19 (11), pp. 2550-2560, 2017.

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Zuin, V G; Budarin, V L; Bruyn, De M; Shuttleworth, P S; Hunt, A J; Pluciennik, C; Borisova, A; Dodson, J; Parker, H L; Clark, J H

Polysaccharide-derived mesoporous materials (Starbon®) for sustainable separation of complex mixtures Journal Article

Faraday Discussions, 202 , pp. 451-464, 2017.

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Kim, S; Escamilla-Pérez, A M; Bruyn, De M; Alauzun, J G; Louvain, N; Brun, N; Macquarrie, D; Stievano, L; Boury, B; Monconduit, L; Mutin, P H

Sustainable polysaccharide-derived mesoporous carbons (Starbon®) as additives in lithium-ion batteries negative electrodes Journal Article

Journal of Materials Chemistry A, 5 (46), pp. 24380-24387, 2017.

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Bruyn, De M; Fan, J; Budarin, V L; Macquarrie, D J; Gomez, L D; Simister, R; Farmer, T J; Raverty, W D; McQueen-Mason, S J; Clark, J H

A new perspective in bio-refining: Levoglucosenone and cleaner lignin from waste biorefinery hydrolysis lignin by selective conversion of residual saccharides Journal Article

Energy and Environmental Science, 9 (8), pp. 2571-2574, 2016.

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Bai, Y; Bruyn, De M; Clark, J H; Dodson, J R; Farmer, T J; Honoré, M; Ingram, I D V; Naguib, M; Whitwood, A C; North, M

Ring opening metathesis polymerisation of a new bio-derived monomer from itaconic anhydride and furfuryl alcohol Journal Article

Green Chemistry, 18 (14), pp. 3945-3948, 2016.

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Pacheco, Alves Costa A; Sherwood, J; Zhenova, A; McElroy, C R; Hunt, A J; Parker, H L; Farmer, T J; Constantinou, A; bruyn, De M; Whitwood, A C; Raverty, W; Clark, J H

Intelligent Approach to Solvent Substitution: The Identification of a New Class of Levoglucosenone Derivatives Journal Article

ChemSusChem, 9 (24), pp. 3503-3512, 2016.

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Borisova, A; Bruyn, De M; Budarin, V L; Shuttleworth, P S; Dodson, J R; Segatto, M L; Clark, J H

A Sustainable freeze-drying route to porous polysaccharides with tailored hierarchical meso- and macroporosity Journal Article

Macromolecular Rapid Communications, 36 (8), pp. 774-779, 2015.

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Budarin, V L; Shuttleworth, P S; Bruyn, De M; Farmer, T J; Gronnow, M J; Pfaltzgraff, L; Macquarrie, D J; Clark, J H

The potential of microwave technology for the recovery, synthesis and manufacturing of chemicals from bio-wastes Journal Article

Catalysis Today, 239 , pp. 80-89, 2015.

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Zhang, Z; Macquarrie, D J; Bruyn, De M; Budarin, V L; Hunt, A J; Gronnow, M J; Fan, J; Shuttleworth, P S; Clark, J H; Matharu, A S

Low-temperature microwave-assisted pyrolysis of waste office paper and the application of bio-oil as an Al adhesive Journal Article

Green Chemistry, 17 (1), pp. 260-270, 2015.

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Kachrimanidou, V; Kopsahelis, N; Papanikolaou, S; Kookos, I K; Bruyn, De M; Clark, J H; Koutinas, A A

Sunflower-based biorefinery: Poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-3-hydroxyvalerate) production from crude glycerol, sunflower meal and levulinic acid Journal Article

Bioresource Technology, 172 , pp. 121-130, 2014.

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Sherwood, J; Bruyn, De M; Constantinou, A; Moity, L; McElroy, C R; Farmer, T J; Duncan, T; Raverty, W; Hunt, A J; Clark, J H

Dihydrolevoglucosenone (Cyrene) as a bio-based alternative for dipolar aprotic solvents Journal Article

Chemical Communications, 50 (68), pp. 9650-9652, 2014.

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Shuttleworth, P S; Bruyn, De M; Parker, H L; Hunt, A J; Budarin, V L; Matharu, A S; Clark, J H

Applications of nanoparticles in biomass conversion to chemicals and fuels Journal Article

Green Chemistry, 16 (2), pp. 573-584, 2014.

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Wu, C; Budarin, V L; Gronnow, M J; Bruyn, De M; Onwudili, J A; Clark, J H; Williams, P T

Conventional and microwave-assisted pyrolysis of biomass under different heating rates Journal Article

Journal of Analytical and Applied Pyrolysis, 107 , pp. 276-283, 2014.

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Fan, J; bruyn, De M; Zhu, Z; Budarin, V; Gronnow, M; Gomez, L D; Macquarrie, D; Clark, J

Microwave-enhanced formation of glucose from cellulosic waste Journal Article

Chemical Engineering and Processing: Process Intensification, 71 , pp. 37-42, 2013.

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Fan, J; Bruyn, De M; Budarin, V L; Gronnow, M J; Shuttleworth, P S; Breeden, S; Macquarrie, D J; Clark, J H

Direct microwave-assisted hydrothermal depolymerization of cellulose Journal Article

Journal of the American Chemical Society, 135 (32), pp. 12728-12731, 2013.

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Pfaltzgraff, L A; Bruyn, De M; Cooper, E C; Budarin, V; Clark, J H

Food waste biomass: A resource for high-value chemicals Journal Article

Green Chemistry, 15 (2), pp. 307-314, 2013.

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Bruyn, De M; Neumann, R

Stabilization of palladium nanoparticles by polyoxometalates appended with alkylthiol tethers and their use as binary catalysts for liquid phase aerobic oxydehydrogenation Journal Article

Advanced Synthesis and Catalysis, 349 (10), pp. 1624-1628, 2007.

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Bruyn, De M; Limbourg, M; Denayer, J; Baron, G V; Parvulescu, V; Grobet, P J; Vos, De D E; Jacobs, P A

Mesoporous Zr and Hf catalysts for chemoselective MPV reductions of unsaturated ketones Journal Article

Applied Catalysis A: General, 254 (2), pp. 189-201, 2003.

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Bruyn, De M; Coman, S; Bota, R; Parvulescu, V I; Vos, De D E; Jacobs, P A

Chemoselective Reduction of Complex α,β-Unsaturated Ketones to Allylic Alcohols over Ir-Metal Particles on β Zeolites Journal Article

Angewandte Chemie - International Edition, 42 (43), pp. 5333-5336, 2003.

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Bruyn, De M; Vos, De D E; Jacobs, P A

Chemoselective Hydrogen Transfer Reduction of Unsaturated Ketones to Allylic Alcohols with Solid Zr and Hf Catalysts Journal Article

Advanced Synthesis and Catalysis, 344 (10), pp. 1120-1125, 2002.

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Coman, S N; Parvulescu, V I; Bruyn, De M; Vos, De D E; Jacobs, P A

Reduction of prostaglandin unsaturated ketones to secondary allylic alcohols by hydrogen transfer over mesoporous-supported PtSn catalysts Journal Article

Journal of Catalysis, 206 (2), pp. 218-229, 2002.

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Thoelen, C; Bruyn, De M; Theunissen, E; Kondo, Y; Vankelecom, I F J; Grobet, P; Yoshikawa, M; Jacobs, P A

Membranes based on poly(γ-methyl-L-glutamate): Synthesis, characterization and use in chiral separations Journal Article

Journal of Membrane Science, 186 (2), pp. 153-163, 2001.

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